DK-SOFC b, long term development

Afdelingen for Materialeforskning

The DK-SOFC b line is targeted towards: 1) decrease of the operation temperature without increasing the area specific resistance, 2) increase of the ro-bustness of the cell, 3) better understanding of mechanisms.

Project description

The overall purpose of the Danish SOFC (Solid Oxide Fuel Cell) programme is to commercialize Danish SOFC technology. The present one-year project forms a part of a multi-year effort. The focus is on the following problems: 1) Bringing down the area-specific internal resistance (ASR) to enable the SOFC stack to operate at 550-650 deg. C. The electrodes of the current, second generation cell have at present an ASR at 600 deg C which is much too high. 2) Improving the cell lifetime, such that the degradation over 40,000 hours will be less than 0.25%/1000 h. 3) Improving cell and electrode robustness, both mechanically and chemically, to a point where the cells can withstand, e.g., thermal cycling, chromium oxide fumes from the metallic interconnect on the air electrode, and sulfur compounds in the fuel gas. An important element in this is to develop a metal supported, redox stable third generation cell. 4) Development of electrodes that can tolerate untreated natural gas (i.e., electrodes that tolerate sulfur and precipitation of carbon). However, these final goals will not be reached in the present one-year project. An important part of the project is the building up of know-how and related patents

Results

The project was carried out as a part of the Danish SOFC program. The DK-SOFC b line is targeted towards: 1) decrease of the operation temperature without increasing the area specific resistance, 2) increase of the ro-bustness of the cell, 3) better understanding of mechanisms. The activities in this project were development of electrodes and electrolyte. A new technique of post test preparation of electrodes was developed in order to study the electrode-electrolyte interface. A correlation between interface structure of the cathode/electrolyte on the one hand and the performance on the other has been established. A new CAHT-SPM = controlled atmos-phere high temperature scanning probe microscope for in-situ measurements at high temperatures has been developed. A patent application on an anode improved with respect to redox stability has been filed

Key figures

Period:
2005 - 2006
Funding year:
2004
Own financial contribution:
9.57 mio. DKK
Grant:
6.50 mio. DKK
Funding rate:
40 %
Project budget:
16.07 mio. DKK

Category

Programme
EFP
Technology
Brint and fuelcells
Case no.
33030-0109

Participants

Danmarks Tekniske Universitet (DTU) (Main Responsible)

Contact

Kontakperson
Mogensen, Mogens
Comtact information
Forskningscenter Risø. Afdelingen for Materialeforskning
P.O. Box 49
DK-4000 Roskilde, Denmark
www.risoe.dtu.dk
Mogensen, Mogens , 46775700, materials@risoe.dk
Øvr. Partnere: IRD Fuel Cells A/S; Haldor Topsøe A/S; Syddansk Univ.; Danmarks Tekniske Universitet

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