New electrode materials for hydrogen production

The project aimed to find new electrode materials for hydrogen development able to replace the costly and rare platinum normally used in PEM fuel cells. The project succeeded in demonstrating that molybdenum sulphide nanoparticles are highly active.
Project description

In the future it will be important to focus more on renewable energy sources and thus there is a need of finding a new energy carrier, which is able to average the time variations of the energy production from renewable sources like solar cells and wind power. Here hydrogen is at the moment considered a possible solution. Thus it would be favorable to be able to produce and convert hydrogen easily. In that respect electrolysis of water into hydrogen can be done eficiently using platinum electrodes, but platinum is both a scarce and expensive metal. Thus there is a high demand for development of new efficient and cheap electrode matenals. The project is based on the recent work, where it was found that Mos_2 nanoparticles could be a usable electrode material on the cathode when hydrogen was produced despite that fact that bulk Mos_2 materials are semiconductors. However, when present in the form of nanoparticles they display conductive edges making them useful as electrode materials. Preliminary investigations showed that Mos_2 which is an inexpensive material in fact can produce hydrogen with an overpotential of only 0,15 volts with respect to a platinum electrode. The aim of the project is to optimize and explore the potential of metal sulfides as hydrogen evolution electrodes by identifying, synthesizing, characterizing, and testing metal sulfide catalysts

Results

The project showed that only edge atoms are active and that it would be advantageous to make them slightly more reactive. The project produced a number of new materials, several of them more usable than the ones initially produced. The project demonstrated that new inexpensive inorganic materials exist, and that costly platinum materials can be replaced through continued development.

Key figures

Period:
2005 - 2008
Funding year:
2004
Own financial contribution:
0.89 mio. DKK
Grant:
3.60 mio. DKK
Funding rate:
80 %
Project budget:
4.49 mio. DKK

Category

Oprindelig title
Nye elektrodematerialer til hydrogen udvikling
Programme
Innovationsfonden
Technology
Brint and fuelcells
Case no.
ENMI 2104-04-0011

Participants

Danmarks Tekniske Universitet (DTU) (Main Responsible)
Partners and economy
Partner Subsidy Auto financing
No entries available.

Contact

Kontakperson
Chorkendorff, Ib (prof.)
Comtact information
DTU Fysik
Fysikvej bygn. 309
DK-2800 Kgs. Lyngby (DK)
Chorkendorff, Ib (prof.), 45253170,
Øvr. Partnere:

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