HyCycle - Center for renewable hydrogen cycling

Institut for Kemi (DTU Kemi)

The EU's and the Danish government's goal of replacing major parts of fossil fuels with sustainable energy sources requires new processes to be developed for conversion and storage of energy, for example in the form of hydrogen. The project seeks to improve hydrogen production by upgrading the splitting of water through electrolysis of photocatalysis.

Project description

A future major change from fossil fuels to renewable energy sources will cause a demand for new processes for energy conversion and storage. The HyCycle Centre has been working on improvements of the efficiency of processes for splitting of water into hydrogen and oxygen by electrolysis using polymeric electrolyte membranes, or by photo catalysis, i.e. when the water is split using a combination of sun light and an electrochemical system.
The project has involved research groups and enterprises specialized within theory, biomimetics, synthesis of materials, electrochemistry and surface coating processes. An important aspect is new electrocatalytic materials, which may substitute or reduce the necessary amounts of platinum and iridium dioxide, normally used in PEM water electrolysis. In this connection, theoretical calculations of various materials types were carried out, and furthermore a considerably increased catalytic activity was demonstrated by new alloys of platinum and other metals. Concerning photocatalysis the  process was improved by a new manganese based catalyst.
Besides electrodematerials and photocatalysts HyCycle also worked with aspects of other materials involved, particularly new polymeric electrolytes and more stable construction materials.
 

Results

A future major change from fossil fuels to renewable energy sources will cause a demand for new processes for energy conversion and storage. The HyCycle Centre has been working on improvements of the efficiency of processes for splitting of water into hydrogen and oxygen by electrolysis using polymeric electrolyte membranes, or by photo catalysis, i.e. when the water is split using a combination of sun light and an electrochemical system.
The project has involved research groups and enterprises specialized within theory, biomimetics, synthesis of materials, electrochemistry and surface coating processes. An important aspect is new electrocatalytic materials, which may substitute or reduce the necessary amounts of platinum and iridium dioxide, normally used in PEM water electrolysis. In this connection, theoretical calculations of various materials types were carried out, and furthermore a considerably increased catalytic activity was demonstrated by new alloys of platinum and other metals. Concerning photocatalysis the process was improved by a new manganese based catalyst.
Besides electrodematerials and photocatalysts HyCycle also worked with aspects of other materials involved, particularly new polymeric electrolytes and more stable construction materials.

Key figures

Period:
2008 - 2011
Funding year:
2007
Own financial contribution:
5.22 mio. DKK
Grant:
14.70 mio. DKK
Funding rate:
74 %
Project budget:
19.92 mio. DKK

Category

Oprindelig title
Center for bæredygtigt brintkredsløb
Programme
Innovationsfonden
Technology
Brint and fuelcells
Case no.
ENMI 2104-07-0041

Participants

Danmarks Tekniske Universitet (DTU) (Main Responsible)

Contact

Kontakperson
Christensen, Erik
Comtact information
Danmarks Tekniske Universitet. Institut for Kemi (DTU Kemi)
Kemitorvet 207
DK-2800 Kgs. Lyngby, Danmark
www.kemi.dtu.dk
Christensen, Erik , 45252306, erc@kemi.dtu.dk
Øvr. Partnere: Danmarks Teknikse Universitet. Institut for Fysik (DTU Fysik). Syddansk Universitet (SDU). Institut for Kemi og Fysik; Syddansk Universitet (SDU). Institut for Kemi-, Bio- og Miljøteknologi; IRD Fuel Cells A/S; Tantalum Technologies A/S; Danish Power Systems ApS
Contact email
erc@kemi.dtu.dk

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