Durable solid oxide electrolysis cells and stacks

This project aims to develop a cost-effective high temperature electrolysis technology based on SOECs. The technology development started from the technology developed for SOFCs and takes advantage of long term research in this area. SOEC is special in the sense that it allows electrolysis of steam and CO2 to produce hydrogen or synthetic fuel.
Project description

It is the purpose of the present project to make a substantial contribution to development of cost competitive electrolysis technology based on solid oxide electrolysis cells. Two critical issues in this context are to improve the durability of the cells and stacks and to increase the power density. Previous research has established that this calls for improved cathodes (water electrodes) and seals that emit less Si than the presently used ones. Economical analysis has shown that it greatly improves the cost competitiveness of the technology if the stacks can be operated at current densities of more than 1.5 A/cm2, which is achievable if the stacks can be operated at temperatures higher than 800 deg. C. In this case the durability of the stack is strongly influenced by the lifetime of the interconnect material, which is consequently also addressed in the project. The research is divided into five different tasks: 1. Cell and stack testing and post-test characterization The purpose is to: 1) Test the performance of components being developed, and 2) to identify the degradation mechanisms and develop counteracting measures. 2. Development of interconnects and interconnect coatings The objective is to develop corrosion resistant interconnects and coatings to allow for stable operation at 850 deg. C. 3. Development of seals The purpose is to develop good seals which only release small amounts Si during operation. 4. Development of durable SOEC cathodes Three different routes for improving the cathode will be pursued. 5. Modelling The optimal design of an SOEC stack will be assessed by modelling

Results
This project focused on identification of degradation mechanisms and development and demonstration of components with improved durability for SOEC. With state-of-the-art Risø solid oxide cells, negligible degradation has been decumented under mild electrolysis operations. Degradation is seen under harsh conditions and is related mostly to the oxygen electrode. Protective coatings of the interconnect components were developed and demonstrated to prolong predicted lifetime by a factor of 2-30 as compared to the uncoated ones. Ag-based braze seals were developed, fulfulling various requirements including TEC matching and leak tightness. (Energy 11)

Key figures

Period:
2008 - 2010
Funding year:
2008
Own financial contribution:
2.53 mio. DKK
Grant:
4.99 mio. DKK
Funding rate:
66 %
Project budget:
7.53 mio. DKK

Category

Oprindelig title
Holdbare fastoxid elektrolyse celler og stakke
Programme
ForskEL
Technology
Brint and fuelcells
Case no.
10045

Participants

Danmarks Tekniske Universitet (DTU) (Main Responsible)
Partners and economy
Partner Subsidy Auto financing
No entries available.

Contact

Kontakperson
Vang Hendriksen, Peter
Comtact information
Danmarks Tekniske Universitet. Risø Nationallaboratoriet for Bæredygtig Energi (Risø DTU). Afdelingen for Brændselsceller og Faststofkemi
Frederiksborgvej 399, Postboks 49
DK-4000 Roskilde
www.risoe.dtu.dk
Tlf.: 46775725
 
Contact email
pvhe@risoe.dtu.dk

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