ENEFOX – Energy Effecient Oxygen Production for a Sustainable Energy System

The research concerns reduction of the CO2 emission in the energy sector by using ceramic membranes in preparation of pure oxygen. The membranes make biomass conversion more efficient and reduce the costs of producing transportation fuels from biomass which make the CO2-neutral transportation more competitive.
 

Reduction of CO2 emissions is a key challenge for society - especially for the energy sector. Ceramic membranes for production of pure oxygen have the potential to become a key technology in this context. Used in conjunction with biomass gasifiers they will allow a more efficient power production and reduce cost of possible down-stream upgrade of the producer gas to synthetic fuels for the transport sector, thereby improving competitiveness of sustainable transport. They can moreover reduce emissions and energy consumption in energy intensive industrial processes like e.g. cement production. The purpose of the project “Enefox” has been to develop oxygen membranes for these two applications. In the project new membrane materials have been developed and the best ways to integrate the membranes in a gasifier and a cement plant have been established. In the project, supplemented with activities in a derived project, we have succeeded in preparing both planar (5*5 cm2) and tubular membranes with a length of up to 50 cm. Subsequent durability test over one month show high and stable oxygen flux. Now follows further upscale and documentation of component robustness, before the technology reaches a maturity allowing use in real plants.
Project description

Widespread availability of cheap, pure oxygen can contribute to a significant reduction of CO2 emissions both in Denmark and worldwide by increasing the efficiency of biomass conversion and by simplifying routes for capture of CO2 from cement production. Present-day oxygen production relies on cryogenic distillation having a very large energy consumption. A promising alternative, pursued in several places in the world, is ion conducting membranes for gas separation. The present project will further oxygen membrane technology with special focus on the use in biomass gasification and cement production. Biomass is an important but also very limited energy resource. This makes it important to use it as efficiently as possible. Use of pure oxygen produced by oxygen membranes will improve the energy efficiency of power generation from biomass gasification and reduce the costs of CO2 neutral transportation fuels made from biomass. An example is DME, one of the most promising clean fuels for transportation, cooking & heating, and power generation. By replacing LPG (liquefied petroleum gas), DME has an enormous market potential in emerging countries, including China. Cement production is globally one of the largest industrial contributors to emission of greenhouse gases. The use of pure oxygen in cement production allows increased use of biomass and waste in the firing. Further, it will make CO2 capture and sequestration from the flue gas stream cheaper and more energy efficient. This is necessary for deep reduction of industry emissions as half of the CO2 emissions are released directly from the calcination of the raw material. The project brings together leading Danish and Chinese research groups with large expertise in ceramic membranes; from industry Danish cement and gasification companies will participate.

Key figures

Period:
2012 - 2016
Funding year:
2011
Own financial contribution:
1.24 mio. DKK
Grant:
6.50 mio. DKK
Funding rate:
84 %
Project budget:
7.74 mio. DKK

Category

Programme
Innovationsfonden
Technology
Brint and fuelcells
Case no.
ENMI 11-116387

Participants

Danmarks Tekniske Universitet (DTU) (Main Responsible)
Partners and economy
Partner Subsidy Auto financing
Danmarks Tekniske Universitet (DTU) 6,50 mio. DKK 0,68 mio. DKK
FLS Miljø A/S 0,18 mio. DKK
HALDOR TOPSØE A/S 0,12 mio. DKK
USTC 0,24 mio. DKK
Central South University 0,02 mio. DKK

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