On-line mass spectrometric measurement of tar from thermal gasification of biomass. Phase 1

This project includes preliminary investigations concerning the possibility for online tar measurements with membrane inlet mass spectrometry (MIMS) in connection with biomass gasification.

Project description

The main purpose of this project is to develop an on-line method of analysing tar for controlling the operation of a thermal biomass gasification plant used for combined power and heat production by gas engines/gas turbines. The analysis method is primarily developed for use as a continuous quality control of the purified gas, before burning in the engine. The analysis method is based on Membrane Inlet Mass Spectrometry (MIMS), by which selected compounds are introduced into the ion source of the mass spectrometer via diffusion through a polymer membrane. Test of the MIMS-system are carried out with selected tar components for optimising the design of the membrane inlet. Temperature Programmed Desorption (TPD) is tested and evaluated for separation of tar components before the mass spectrometric analysis. A performance test of the MIMS-system is made at a few plants for gasification of biomass

Results

The MIMS sampling method has been tested in connection with tar measurement on raw gas from the updraft gasifier and clean gas from the downdraft gasifier. The sampling method has been tested with regard to obstruction of the membrane inlet and to qualitative and quantitative properties. The need for detailed investigations has been determined on the basis of the preliminary investigation and the possibility of using the method in future has been discussed

Key figures

Period:
1999 - 2000
Funding year:
1999
Own financial contribution:
0.18 mio. DKK
Grant:
0.80 mio. DKK
Funding rate:
82 %
Project budget:
0.98 mio. DKK

Category

Oprindelig title
On-line tjæremåling med massespektrometri i forbindelse med termisk forgasning af biomasse
Programme
EFP
Technology
Bio and waste
Project type
Analyse
Case no.
1383/99-0006

Participants

Teknologisk Institut (Main Responsible)
Partners and economy
Partner Subsidy Auto financing
Mins Systems
Danmarks Tekniske Universitet (DTU)

Contact

Kontakperson
Pedersen, Karsten
Comtact information
Teknologisk Institut. Miljø
Teknologiparken
DK-8000 Århus C, Denmark
Andersen, Erik ; Projektleder: Pedersen, Karsten (akad.ing.), 89438943,
Øvr. Partnere: Mins Systems; Forskningscenter Risø

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