H2CAP-Hydrogen assisted catalytic biomass pyrolysis for green fuels

The project aims at developing a new process for producing high quality bio oil which can be used as fuel for the transportation sector using current infrastructure. The process is catalytic hydropyrolysis of biomass with hydrogenation to remove oxygen. The process utilizes only non-food biomass.

Project description

In order to be independent of fossil fuels it is vital to convert biomass to liquid fuels which can be integrated in the current transportation infrastructure. Biomass can be converted to bio-oil, along with char and gas, by flash heating (pyrolysis) to 400 to 500 °C in oxygen free atmosphere. The properties of this bio-oil are very different from crude oil, since it is made of oxygen containing hydrocarbons and contains large amount of water, thus it requires upgrading. The aim of this project is to develop an integrated process of high-pressure pyrolysis of biomass with catalytic hydrotreating before condensation of the liquid product. This bio-oil will be a mixture of diesel and gasoline fuels. The process utilizes non-food, second generation biomass like straw and wood; hydrogen produced by electrolysis using sustainable sources like wind and solar energy and it is expected to have a higher energy recovery compared to bio-ethanol production. Lab-scale process equipment for continuous, pressurized pyrolysis will be constructed in order to demonstrate and optimize the process and develop suitable catalysts. The produced oil will be extensively characterized for composition, viscosity, energy density and miscibility with fossil fuels in order to evaluate its fuel properties. The project is a consortium of leading research experts in Denmark (DTU), Germany (KIT) and USA (Stanford) and the company Haldor Topsøe A/S.

Key figures

Period:
2014 - 2018
Funding year:
2013
Own financial contribution:
3.51 mio. DKK
Grant:
14.41 mio. DKK
Funding rate:
80 %
Project budget:
17.92 mio. DKK

Category

Programme
Innovationsfonden
Technology
Bio and waste
Project type
Forskning
Case no.
1305-00015B

Participants

Danmarks Tekniske Universitet (DTU) (Main Responsible)
Partners and economy
Partner Subsidy Auto financing
Danmarks Tekniske Universitet (DTU) 11,50 mio. DKK 1,70 mio. DKK
Danmarks Tekniske Universitet (DTU) 1,30 mio. DKK 0,22 mio. DKK
Karlsruhe Insitute of Technology (KIT) 0,80 mio. DKK 0,08 mio. DKK
Stanford University 0,82 mio. DKK
HALDOR TOPSØE A/S 1,50 mio. DKK

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